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PARAMAGNETIC QUALITIES OF FREE OXYGEN

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  • PARAMAGNETIC QUALITIES OF FREE OXYGEN

    PARAMAGNETIC - "Having a magnetic permeability greater than unity."


    (From:


    DICTIONARY OF TECHNICAL TERMS FOR AEROSPACE USE)


    "In the 1840s Michael Faraday discovered that oxygen is attracted to


    a magnet.


    Almost a century later, in 1925, Robert Mulliken explained why


    oxygen is magnetic


    using the recently developed quantum theory. His analysis shows


    that molecular


    oxygen has two unpaired electrons in its lowest energy state."


    (From: http://www.bio-laser.org/singox.html)


    Free oxygen in solution is paramagnetic; free nitrogen is not.


    Disolved oxygen


    can be driven out of water by bubbling pure nitrogen through it for


    20 minutes or


    by boiling it. (See posting # 91)


    However it seems that with plastic toroidal forms water WILL


    reacquire free oxygen


    over a 7 to 14 day period. This is due to the permeability of most


    plastics, and I am told


    is explained by "Henry's Law" which is an equation that shows the


    relationship be-


    tween pressure and solubility of gases in liquids.


    The primary effect, for our purposes, of the reaquistion of free


    oxygen, is that


    the signal decay time is decreased. Jim Koehler's PPM design


    addresses this prob-


    lem because he measures the signal rapidly enough that decrease has


    no practical


    effect on the accuracy of the reading. This may be true of other


    units also.


    Nevertheless this still leaves us with the question of IF the


    decreased decay time


    is the ONLY effect of the paramagnetic qualities of the free oxygen.


    In other


    words - has the amplitude or quality of the signal also suffered


    some degradation


    because of the free oxygen contained in the proton rich fluid


    (distilled water in


    this case)?


    I understand that this sounds like nitpicking BUT MANY companies


    make paramagnetic


    oxygen analyzers and the units I have looked at cost in excess of


    US$5,000.00.


    Therefore somebody seems to think that the effects are significant.


    The aforemen-


    tioned units are for medical applications often in connection with


    magnetic


    resonance imaging (MRI).


    Hopefully someone that is qualified in chemistry, will consider


    these questiona and


    put forth some ideas on the subject.


    The one thing I have come up with so far is HINT that Temone MIGHT


    keep proton


    rich fluids from reacquiring free oxygen and this might be the


    reason that Geonics


    and others use it in their toroidal sensors. I PREVIOUSL assumed


    that Temone


    was used to make a proton rich fluid, whereas I NOW have the


    opinion that it is an


    ADDITIVE to the proton rich fluid that is used.


    Best to all,


    Dale
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